Wagner plot | Ricerc@Sapienza

Relationship between the Auger parameter and the ground state valence charge of the core-ionized atom: the case of Cu(I) and Cu (II) compounds

We develop a simple semiempirical model that correlates the Auger parameter to the ground state valence charge of the core-ionized atom with closed shell electron configuration. Until now, the Auger parameter was employed to separate initial and final state effects that influence the core electron binding energy. The model is applied to Cu(I) and Cu (II) compounds with the Auger parameter defined as α' = Eb FL (2p3/2) + Ek FL (L3M45M45;1G).

Physical genetics: Cross-breeding density functional theory and X-ray photoelectron spectroscopy to rationalize chemical shifts of binding energies in solid compounds

Like other spectroscopic methods XPS and AES show characteristic chemical shifts depending on the elemental matrix of a compound, however, a satisfactory rationalization of the variance of such values is often difficult. By an extension of a previous approach we present a theory in a unifying equation which combines several parameters - some of them resulting from DFT calculations - which influence the energy of the outgoing electrons and thereby seemingly the binding energy.