Ricerc@Sapienza

Mortar grouting is often used in masonry constructions to mitigate structural decay and repair damage by filling cracks and voids, resulting in an improvement in mechanical properties. This paper presents an original experimental investigation on grout with added carbon nanotubes (CNTs). The samples were prepared with different percentages of CNTs, up to 1.2 wt% with respect to the binder, and underwent three‐point bending tests in crack mouth opening displacement mode and compressive tests.

Improving energy dissipation in lightweight polymer nanocomposites to achieve environmentally friendly and mechanically stable structures has reached a limit because of the low-density electrostatic interactions that can be harnessed through the stick-slip mechanism between carbonaceous nanofillers and polymeric chains wrapped around them. In this paper, the atomic friction between the two nanocomposite components is greatly amplified by locally increasing the density of the energetically higher noncovalent bonds.

Numerical and analytical investigations into the aeroelastic response of thin nanocomposite panels are discussed. The mechanical data of the nanocomposite plates with different weight fractions of randomly oriented carbon nanotubes (CNT) are obtained via an extensive experimental campaign based on dynamic mechanical analysis (DMA). Panel flutter induced by high supersonic flows is studied through both linear and nonlinear dynamic analyses aimed to investigate the effect of the CNT weight fraction onto the flutter and post-flutter condition.

This article presents a comparative review of the most commonly used nano-additives for bituminous mixtures: nanoclays (NC), nanosilicates, carbon nanotubes (CNTs), graphene nanoplatelets (GNPs), nano-calcium oxide (CaO), and nano-titanium dioxide (TiO2). In this study, the mechanical behavior of the obtained additive mixture is evaluated. According to the revised literature, the results strongly depend on type, concentration, and dispersal of used nano-additive.

Lattice Boltzmann method ability is improved to simulate the mixed convection of Water / FMWCNT nanofluid inside a two dimensional microchannel. The influences of gravity on hydrodynamic and thermal domains are studied while the microchannel walls are imposed by a constant thermal heat flux at three different case studies as no-gravity, Ri=1 and Ri=10. The flow Reynolds number is chosen as one and the liquid micro flow conditions are involved by B = 0.005, B = 0.01 and B = 0.02. The mass fraction of carbon nanotubes in water are selected as ϕ=0, ϕ=0.1% and ϕ=0.2%.

In this chapter we review the impact behavior of composite structures consisting of long-fiber reinforcement and thermosetting matrices based on epoxy resins loaded with carbon nanoparticles. Different types of nanotubes (single-, multi-walled, coiled) and graphene nanoplatelets are considered as carbon reinforcement of the polymer matrix.

This paper describes, for the first time, the use of oxidized buckypaper (BP) as a sorbent membrane of a stir-disc solid phase extraction module. The original device, consisting of a BP disc (d = 34 mm) enveloped in a polypropylene mesh pouch, was designed to extract organic micropollutants (OMPs) from environmental water samples in dynamic mode. High-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) was used to analyze the extracts.

This paper describes the development of an original micro-solid phase extraction device and its evaluation for the isolation of F2-isoprostanes (F2-IsoPs) from cord and maternal plasma samples. The unit is very simple and consists in a rotating disc (1.8 cm diameter) of oxidized buckypaper (BP), enwrapped in a polypropylene mesh pouch.

Protein and peptide phosphorylation regulate numerous pathological processes, however, their characterization is challenging due to their low abundance and transient nature. Therefore, nanomaterials are being developed to address this demanding task. In particular, carbon nanostructures are attracting interest as scaffolds for functional nanocomposites, yet only isolated studies exist on the topic, and little is known on the effect of nanocarbon morphology on templating nanocomposites.

Benzo-15-crown-5 ether supported on multi-wall carbon nanotubes (MWCNTs) by tethered poly(amidoamine) (PAMAM) dendrimers efficiently coordinated methyltrioxorhenium in the selective oxidation of olefins to epoxides. Environmentally friendly hydrogen peroxide was used as a primary oxidant. Up to first and second generation dendrimer aggregates were prepared by applying a divergent PAMAM methodology. FT-IR, XRD and ICP-MS analyses confirmed the effective coordination of methyltrioxorhenium by the benzo-15-crown-5 ether moiety after immobilization on MWCNTs.