Ricerc@Sapienza

The electrochemical oxidation of theophylline was investigated by controlled potential electrolysis in two different organic solvents and in water for comparison. The anodic oxidation was monitored by cyclic voltammetry in situ and UV‐Vis spectrophotometry ex situ and the final electrolyzed solutions were analyzed by tandem mass spectrometry after chromatographic separation with an HPLC‐PDA‐ESI‐MS/MS system.

Electrochemical studies on a series of new conjugated oligothiophene derivatives are reported. The molecular architectures (D−A and A−D−A) of these compounds present different donor cores (thiophene, bithiophene) with different numbers of 3‐octylthiophene units (that act as π‐bridge and solubilizing components). The acceptor end groups adopted were, in all the cases, ethyl cyanoacrylate units. The results from voltammetric experiments confirm the close relationship between the structure of these oligothiophenes and their electrochemical behavior.

The electrochemical reduction of caffeine, never carried out previously, yielded in DMF-Et 4 NBF 4 N -formyl- N,1-dimethyl-4-(methylamino)-1 H -imidazole-5-carboxamide, a highly functionalized imidazole product derived from the opening of the uracil ring. This reactivity is different from that of the methylated salt of caffeine, the cathodic reduction of which leads to the opening of the imidazole ring.

N-Heterocyclic olefin (NHO) can be generated by simple
cathodic reduction of BDMImBF
4
-DMF solution or neat
BDMImBF
4
(BDMImBF
4
=
1-butyl-2,3-dimethyl-1
H
-imidazolium
tetrafluoroborate; DMF
=
dimethylformamide). In the latter case,
the use of any organic solvent and chemical base is avoided. To
prove the presence of NHO, its adduct with benzaldehyde was
isolated. The electrochemical behavior of NHO is very similar to

Wafer-scale integration of reduced graphene oxide with H-terminated Si(1 1 1) surfaces has been accomplished by electrochemical reduction of a thin film of graphene oxide deposited onto Si by drop casting. Two reduction methods have been assayed and carried out in an acetonitrile solution. The initial deposit was subjected either to potential cycling in a 0.1 M TBAPF 6 /CH 3 CN solution at scan rates values of 20 mV s −1 and 50 mV s −1 , or to a potentiostatic polarization at E λ,c = −3 V for 450 s.