entropic barriers

Exact moment analysis of transient dispersion properties in periodic media

This paper develops a homogenization approach, based on the introduction of exact local and integral moments, to investigate the temporal evolution of effective dispersion properties of point-sized and finite-sized particles in periodic media. The proposed method represents a robust and computationally efficient continuous approach, alternative to stochastic dynamic simulations. As a case study, the exact moment method is applied to analyze transient dispersion properties of point-sized and finite-sized particles in sinusoidal tubes under the action of a pressure-driven Stokes flow.

Laminar dispersion at low and high Peclet numbers in a sinusoidal microtube: point-size versus finite-size particles

his paper adopts Brenner’s homogenization theory to investigate dispersion properties, over a wide range of Peclet values, of point-size and finite-size particles in sinusoidal cylindrical microchannels in the presence of a pressure-driven Stokes flow field. The periodic alternation of entropic barriers/traps can unexpectedly increase the effective finite-size particle velocity as well as decrease the effective dispersion coefficient for both point-size and finite-size particles, for large values of the radial Peclet number.

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