Ricerc@Sapienza

Chalcopyrite leaching in acidic ferric sulfate media at ambient temperature exhibits slow kinetics due to the formation of passivation layers on chalcopyrite surfaces. In this study, we investigated the use of potassium iodide to assist chalcopyrite leaching and proposed mechanisms by which iodide enhanced the leaching efficiency. The effect of ferric concentration, temperature and iodide concentration on chalcopyrite leaching was studied by factorial experimental design and statistical analysis of data using the analysis of variance (ANOVA) method.

The aim of this work was to investigate the aggregation of metallic iron nanoparticles in a Rushton equipped agitated vessel open at the atmosphere. The particles were synthetized using oxygen-free reagent solutions and subsequently were suspended in water in an open lab-scale agitated vessel. The particle size distribution, zeta-potential, pH and Fe(0) content were monitored over the time, up to the complete oxidation of the particles.

This article proposes the aqueous system Cu-Fe(0)/NO3 ? mathematical modelling through a classical shrinking core model, taking into account the presence of dissolved oxygen in the reaction medium and considering it in the model equation. In this work the nitrate reduction to ammonia was assumed to occur onto the lab-made bimetallic nano zero-valent iron (nZVI) surface, simultaneously with the nZVI consumption due to the oxidation carried out by dissolved oxygen.