Ricerc@Sapienza

Hydrophobic (nano)textured surfaces, also known as superhydrophobic surfaces, have a wide range of technological applications, including in the self-cleaning, anti-moisture, anti-icing, anti-fogging and friction/drag reduction fields, and many more. The accidental complete wetting of surface textures, which destroys superhydrophobicity, and the opposite process of recovery are two crucial processes that can prevent or enable the technological applications mentioned before. Understanding these processes is key to designing surfaces with tailored wetting and recovery properties.

In order to deepen the mechanisms at the basis of mold surface replication onto the molded plastic surface, a novel experimental approach is proposed. Up to 20 different mold surface textures were made by machining with repetitive patterns of peaks and valleys. Mold replication tests were performed by over-molding of high density polyethylene (HDPE) on steel inserts. The surface morphology of inserts and injection molded parts was acquired by surface analyzer, and all the main roughness parameters were extracted and compared as well as the geometrical profiles.

We report on the detection of an angiogenic molecule Vascular Endothelial Growth Factor (VEGF) in different biological matrices by means of a new integrated biosensing platform exploiting the properties of Bloch surface waves. The new platform takes advantage of a tandem configuration, in which both label-free and enhanced fluorescence detection are implemented. Specifically designed one dimensional photonic crystals were deposited directly on disposable and low cost plastic biochips.

Adding titanium to a hot-dip galvanising bath, a coloured oxide film due to interference effect was obtained on iron samples; different colours were achieved varying the bath temperature in the range of 520–600°C.

Gold nanoparticles with an average diameter of 10 nm, functionalized by the dye molecule rhodamine B isothiocyanate, have been synthesized. The resulting material has been extensively characterized both chemically, to investigate the bonding between the dye molecules and the nanoparticles, and physically, to understand the details of the aggregation induced by interaction between dye molecules on different nanoparticles.

In the field of restoration of cultural heritage, it has been developed coatings containing nanoparticles having multifunctional features, to protect stone materials against environmental degrading agents. Detecting such nanoparticle concentration within the coating, can represent a challenging issue because its monitoring over time can provide insights about the treatment durability. This paper deals with a theoretical basis to develop an instrumental method to fulfil this requirement.

The adoption of a-SiOx:H films obtained by PECVD in heterojunction solar cells is a key to further increase their efficiency, because of its transparency in the UV with respect to the commonly used a-Si:H. At the same time this layer must guarantee high surface passivation of the c-Si to be suitable in high efficiency solar cell manufacturing. On the other hand the application of amorphous materials like a-Si:H and SiNx on the cell frontside expose them to the mostly energetic part of the sun spectrum, leading to a metastability of their passivation properties.

The theoretical computational modeling of large conformational transitions occurring in biomolecules still represents a challenge. Here, we present an accurate "in silico" description of the activation and deactivation mechanisms of human c-Src kinases, a fundamental process regulating several crucial cell functions.