theoretical calculations

VUV Photofragmentation of Chloroiodomethane: The Iso-CH2I–Cl and Iso-CH2Cl–I Radical Cation Formation

Dihalomethanes XCH2Y (X and Y= F, Cl, Br and I) are a class of compounds involved in several processes leading to the release of halogen atoms, ozone consumption and aerosol particle formation. Neutral dihalomethanes have been largely studied, but chemical physics properties and processes involving their radical ions, like the pathways of their decomposition, have not been completely investigated. In this work the photodissociation dynamics of the ClCH2I molecule has been explored in the photon energy range 9-21 eV using both VUV rare gas discharge lamps and synchrotron radiation.

Structure and electrophysical properties of polyvinylidene fluoride (PVDF)/magnetite nanocomposites

In the present study, the effect of magnetite (Fe3O4) nanoparticles on the structural and dielectric properties of poly(vinylidene fluoride) (PVDF) matrix was investigated. Distribution of Fe3O4 nanoparticles in the polymer matrix has been studied by scanning electron microscopy (JEOL JSM-7600 F). The structure of the nanocomposite samples was investigated by the X-ray diffraction and Fourier-transform infrared spectroscopy. It was shown that the dielectric permittivity of PVDF + Fe3O4 nanocomposite samples was gradually increased up to 7 wt% of Fe3O4 content.

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