Vanadium hydroxide clusters in the gas phase: bond-forming reactions of doubly-charged negative ions by SO2-promoted V-O bond activation.

2017

CHEMISTRY-A EUROPEAN JOURNAL

Vanadium hydroxide clusters in the gas phase: bond-forming reactions of doubly-charged negative ions by SO2-promoted V-O bond activation.

01 Pubblicazione su rivista

Troiani Anna, Rosi Marzio, Garzoli Stefania, Salvitti Chiara, DE PETRIS Giulia

DOI: 10.1002/chem.201702165

ISSN: 0947-6539

The gas-phase reactivity of doubly-charged vanadium hydroxides anions with SO2 has been studied by experimental and computational methods. The obtainedresults highlight the role of sulfur dioxide in promoting unprecedented bond-forming reactions, which produce singly-charged products by breaking the VxOy skeleton or a terminal VObond.

doubly-charged anions ion-molecule reactions mass spectrometry sulfur dioxide vanadium