Andrea Lapi

Pubblicazioni

Titolo Pubblicato in Anno
Solvation structure of lanthanide(iii) bistriflimide salts in acetonitrile solution: A molecular dynamics simulation and EXAFS investigation PHYSICAL CHEMISTRY CHEMICAL PHYSICS 2019
N-Hydroxyphthalimide: a hydrogen atom transfer mediator in hydrocarbon oxidations promoted by nonheme iron(IV)-Oxo complexes JOURNAL OF ORGANIC CHEMISTRY 2019
On the coordination of Zn2+ion in Tf2N-based ionic liquids: Structural and dynamic properties depending on the nature of the organic cation PHYSICAL CHEMISTRY CHEMICAL PHYSICS 2018
Influence of counterions on the hydration structure of Lanthanide ions in dilute aqueous solutions JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL 2018
Oxidative functionalization of aliphatic and aromatic amino acid derivatives with H2O2 catalyzed by a nonheme imine based iron complex RSC ADVANCES 2018
Ce3+and La3+ions in ethylammonium nitrate: A XANES and molecular dynamics investigation CHEMICAL PHYSICS LETTERS 2018
Role of electron transfer processes in the oxidation of aryl sulfides catalyzed by nonheme iron complexes PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 2017
Aerobic oxidation of 4-Alkyl-N,N-dimethylbenzylamines catalyzed by N-hydroxyphthalimide: Protonation-Driven control over regioselectivity JOURNAL OF ORGANIC CHEMISTRY 2017
Hydrogen atom transfer (HAT) processes promoted by the quinolinimide-N-oxyl radical. A kinetic and theoretical study JOURNAL OF ORGANIC CHEMISTRY 2017
Toward the Elucidation of the Competing Role of Evaporation and Thermal Decomposition in Ionic Liquids: A Multitechnique Study of the Vaporization Behavior of 1-Butyl-3-methylimidazolium Hexafluorophosphate under Effusion Conditions JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL 2017
Oxidation of Aryl Diphenylmethyl Sulfides promoted by a Nonheme Iron(IV)-Oxo Complex: Evidence for an Electron Transfer-Oxygen transfer mechanism JOURNAL OF ORGANIC CHEMISTRY 2016
Thermodynamic study on six tricyclic nitrogen heterocyclic compounds by thermal analysis and effusion techniques THERMOCHIMICA ACTA 2016
Kinetic study of the reaction of the phthalimide-n-oxyl radical with amides: structural and medium effects on the hydrogen atom transfer reactivity and selectivity JOURNAL OF ORGANIC CHEMISTRY 2016
Electron transfer mechanism in the oxidation of Aryl 1-Methyl-1-phenylethyl sulfides promoted by nonheme Iron(IV)-oxo complexes: the rate of the oxygen rebound process JOURNAL OF ORGANIC CHEMISTRY 2016
Unveiling the complex network of interactions in Ionic Liquids: A combined EXAFS and Molecular Dynamics approach JOURNAL OF PHYSICS. CONFERENCE SERIES 2016
Structural properties of geminal dicationic ionic liquid/water mixtures: a theoretical and experimental insight PHYSICAL CHEMISTRY CHEMICAL PHYSICS 2016
Photosensitized oxidation of aryl benzyl sulfoxides. Evidence for nucleophilic assistance to the C-S bond cleavage of aryl benzyl sulfoxide radical cations JOURNAL OF ORGANIC CHEMISTRY 2015
Isotope effect profiles in the N-demethylation of N,N-dimethylanilines: a key to determine the pK(a) of nonheme Fe(III)-OH complexes CHEMICAL COMMUNICATIONS 2015
C-H bond oxidation catalyzed by an imine-based iron complex. A mechanistic insight INORGANIC CHEMISTRY 2015

ERC

  • PE5_17

Interessi di ricerca

Dr. Andrea Lapi has strong background in physical organic chemistry. His main research activity regards the study of the property and reactivity of aromatic radical cations, the role of electron transfer steps in organic and bioorganic reactions, the mechanism of enzymatic and biomimetic oxidation of organic substrates, the reactivity of singlet oxygen with aromatic compounds and the properties of ionic liquids as reaction media. In the last years he devoted his interests towards the study of the reaction mechanisms involved in the oxidation of organic substrates promoted by N-oxyl radicals and non-heme iron complexes.

Keywords

aerobic oxidations
aerobic oxidations
free radicals
reaction mechanisms
biomimetic complexes
catalysis
: ionic liquids
hydrogen atom transfer
electron transfer
Singlet oxygen

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