Giorgio Olivo

Pubblicazioni

Titolo Pubblicato in Anno
Imine-based Iron and Manganese Complexes as Catalysts for Alkane Functionalization Alkane Functionalization 2019
Oxidative functionalization of aliphatic and aromatic amino acid derivatives with H2O2 catalyzed by a nonheme imine based iron complex RSC ADVANCES 2018
Controlling Selectivity in Aliphatic C−H Oxidation through Supramolecular Recognition CHEMISTRY-A EUROPEAN JOURNAL 2018
Role of electron transfer processes in the oxidation of aryl sulfides catalyzed by nonheme iron complexes PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 2017
Formation of imidazo[1,5-a]pyridine derivatives due to the action of Fe2+ on dynamic libraries of imines JOURNAL OF ORGANIC CHEMISTRY 2017
Following a chemical reaction on the millisecond time scale by simultaneous X-ray and UV/Vis spectroscopy THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS 2017
Direct hydroxylation of benzene and aromatics with H2O2 catalyzed by a self-assembled iron complex: evidence for a metal-based mechanism CATALYSIS SCIENCE & TECHNOLOGY 2017
Supramolecular recognition allows remote, site-selective C-H oxidation of methylenic sites in linear amines ANGEWANDTE CHEMIE. INTERNATIONAL EDITION 2017
Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations JBIC 2017
Non-heme Imine-based iron complexes as catalysts for oxidative processes ADVANCED SYNTHESIS & CATALYSIS 2016
Oxidation of Aryl Diphenylmethyl Sulfides promoted by a Nonheme Iron(IV)-Oxo Complex: Evidence for an Electron Transfer-Oxygen transfer mechanism JOURNAL OF ORGANIC CHEMISTRY 2016
Alcohol oxidation with H2O2 catalyzed by a cheap and promptly available imine based iron complex ORGANIC & BIOMOLECULAR CHEMISTRY 2016
Electron transfer mechanism in the oxidation of Aryl 1-Methyl-1-phenylethyl sulfides promoted by nonheme Iron(IV)-oxo complexes: the rate of the oxygen rebound process JOURNAL OF ORGANIC CHEMISTRY 2016
Biologically Inspired C−H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes CHEMISTRY - AN ASIAN JOURNAL 2016
Isotope effect profiles in the N-demethylation of N,N-dimethylanilines: a key to determine the pK(a) of nonheme Fe(III)-OH complexes CHEMICAL COMMUNICATIONS 2015
C-H bond oxidation catalyzed by an imine-based iron complex. A mechanistic insight INORGANIC CHEMISTRY 2015

ERC

  • PE5_13
  • PE5_16
  • PE5_17

KET

  • Sustainable technologies & development

Interessi di ricerca

1) Supramolecular control of reactivity and selectivity in radical and radical-like reactions.

2) Bioinspired oxidation via sustainable Fe, Mn and Cu catalysis

3) Amination of organic compounds via N-O bond activation

4) Fundamental understanding of organic and inorganic reactivity

Keywords

C-H functionalization
hydrogen atom transfer
supramolecular catalysis
biomimetic complexes

Progetti di Ricerca

Gruppi di ricerca

SupRa Lab Rome

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